Method and apparatus for filling a gap

ABSTRACT

According to the invention a method for filling one or more gaps created during manufacturing of a feature on a substrate is provided by providing the substrate in a reaction chamber and providing a deposition method. The deposition method comprises; providing an anisotropic plasma to bombard a bottom area of a surface of the one or more gaps with ions thereby creating adsorption sites at the bottom area; introducing a first reactant to the substrate; and, allowing the first reactant to react with the adsorption sites at the bottom area of the surface to fill the one or more gaps from the bottom area upwards.

FIELD

The present invention generally relates to methods and apparatus for manufacturing electronic devices.

More particularly, the invention relates to a method and apparatus for filling one or more gaps created during manufacturing of a feature on a substrate by:

providing the substrate in a reaction chamber and providing a deposition method comprising;

introducing a first reactant to the substrate; and,

allowing the first reactant to react at the bottom area of the surface to fill the one or more gaps.

BACKGROUND

During manufacturing of an integrated circuit on a substrate gaps e.g. trenches can be created on the substrate. Refilling the trenches can take a variety of forms depending upon the specific application.

The basic trench filling process may be subjected to drawbacks, including void formation in the trench during refill. Voids may be formed when the refilling material forms a constriction near the top of the trench before it is completely filled. Such voids may compromise device isolation of the devices on the integrated circuit (IC) as well as the overall structural integrity of the IC. Unfortunately, preventing void formation during trench fill may often place minimum size constraints on the trenches themselves, which can limit device packing density of the device.

If the trenches are filled for device isolation a key parameter in measuring the effectiveness of device isolation may be the field threshold voltage, that is, the voltage necessary to create a parasitic current linking adjacent isolated devices. The field threshold voltage may be influenced by a number of physical and material properties, such as trench width, dielectric constant of the trench filling material, substrate doping, field implant dose and substrate bias.

Void formation may be mitigated by decreasing trench depth and/or tapering trench sidewalls so that the openings may be wider at the top than at the bottom. A trade off in decreasing the trench depth may be reducing the effectiveness of the device isolation, while the larger top openings of trenches with tapering sidewalls use up additional integrated circuit real estate.

SUMMARY

It is an objective, for example, to provide an improved or at least alternative gap filling method.

Accordingly, there is provided a method for filling one or more gaps created during manufacturing of a feature on a substrate by providing a deposition method comprising;

providing an anisotropic plasma to bombard a bottom of a surface of the one or more gaps with ions thereby creating adsorption sites at the bottom;

introducing a first reactant to the substrate; and,

allowing the first reactant to react with the created adsorption sites at the bottom of the surface to fill the one or more gaps from the bottom area upwards.

The anisotropic plasma will bombard the bottom of the surface of the one or more gaps with ions and thereby create adsorption sites at the bottom. The first reactant will be introduced to the substrate in the reaction chamber and allowed to react with the adsorption sites at the bottom of the surface to fill the one or more gaps from the bottom upwards.

According to a further embodiment there is provided a semiconductor processing apparatus to provide an improved or at least alternative gap filling method. The apparatus comprising:

one or more reaction chambers for accommodating a substrate provided with gaps created during manufacturing of a feature on the substrate;

a plasma gas source for a plasma gas in gas communication via a plasma gas valve with one of the reaction chambers;

a radio frequency power source constructed and arranged to create an anisotropic plasma of the plasma gas to bombard a bottom of a surface of the one or more gaps with ions thereby creating adsorption sites at the bottom;

a first source for a first reactant in gas communication via a first valve with one of the reaction chambers; and,

a controller operably connected to the plasma and first gas valve, and the radio frequency power source and configured and programmed to control:

a timing and an amount of the plasma gas, via the plasma gas valve, and the radio frequency source to use the plasma gas source and the radiofrequency power source to create an anisotropic plasma to bombard the bottom of the surface of the one or more gaps with ions thereby creating adsorption sites at the bottom; and,

a timing and an amount of the first reactant to deposit the first reactant in the bottom of the surface of the gap to react with the created adsorption sites at the bottom.

For purposes of summarizing the invention and the advantages achieved over the prior art, certain objects and advantages of the invention have been described herein above. Of course, it is to be understood that not necessarily all such objects or advantages may be achieved in accordance with any particular embodiment of the invention.

Thus, for example, those skilled in the art will recognize that the invention may be embodied or carried out in a manner that achieves or optimizes one advantage or group of advantages as taught or suggested herein without necessarily achieving other objects or advantages as may be taught or suggested herein.

All of these embodiments are intended to be within the scope of the invention herein disclosed. These and other embodiments will become readily apparent to those skilled in the art from the following detailed description of certain embodiments having reference to the attached figures, the invention not being limited to any particular embodiment(s) disclosed.

BRIEF DESCRIPTION OF THE DRAWINGS

These and other features, aspects, and advantages of the invention disclosed herein are described below with reference to the drawings of certain embodiments, which are intended to illustrate and not to limit the invention.

FIG. 1A is a schematic representation of a PEALD (plasma-enhanced atomic layer deposition) apparatus for filling a gap usable in an embodiment of the present invention.

FIG. 1B illustrates a schematic representation of a precursor supply system using a flow-pass system (FPS) usable in an embodiment of the present invention.

FIG. 2 is a flowchart of a method for filling a gap in accordance with a first embodiment.

DETAILED DESCRIPTION OF EXEMPLARY EMBODIMENTS

Although certain embodiments and examples are disclosed below, it will be understood by those in the art that the invention extends beyond the specifically disclosed embodiments and/or uses of the invention and obvious modifications and equivalents thereof. Thus, it is intended that the scope of the invention disclosed should not be limited by the particular disclosed embodiments described below.

FIG. 2 is a flowchart of a method in accordance with at least one embodiment of the invention in which one or more gaps created during manufacturing of a feature on a substrate may be filled by a deposition method 100. The gaps may be less than 40 or even 20 nm wide. The gaps may be more than 40, 100, 200 or even 400 nm deep.

The deposition method may comprise in a first step 110 providing an anisotropic plasma to bombard a bottom of a surface of the one or more gaps with ions thereby creating adsorption sites at the bottom. The bottom of the surface of the one or more gaps may be defined as the lower, 10% of the total height of the gap including the bottom itself.

The anisotropic plasma may comprises a noble gas plasma such as a helium or argon plasma to bombard the bottom of the surface of the one or more gaps to create dangling bonds on the exposed surface.

The anisotropic plasma can be created using an apparatus illustrated in FIG. 1A, for example. FIG. 1A is a schematic view of a PEALD apparatus, desirably in conjunction with controls programmed to conduct the sequences described herein, usable in some embodiments of the present invention. By providing a pair of electrically conductive flat-plate electrodes 4, 2 in parallel and facing each other in the interior 11 (reaction zone) of a reaction chamber 3, applying HRF power (13.56 MHz or 27 MHz) 20 to one side, and electrically grounding the other side 12, an anisotropic plasma is excited between the electrodes.

A temperature regulator is provided in a lower stage 2 (the lower electrode), and a temperature of a substrate 1 placed thereon is kept constant at a given temperature. The upper electrode 4 serves as a shower plate as well, and a plasma gas (e.g. noble gasses such as argon or helium) are introduced into the reaction chamber 3 through a gas line 21 and through the shower plate 4 to create the plasma.

In the reaction chamber 3, a circular duct 13 with an exhaust line 7 may be provided, through which gas from the interior 11 of the reaction chamber 3 may be exhausted. A transfer chamber 5 disposed below the reaction chamber 3 may be provided with a seal gas line 24 to introduce seal gas into the interior 11 of the reaction chamber 3 via the interior 16 (transfer zone) of the transfer chamber 5 wherein a separation plate 14 for separating the reaction zone and the transfer zone is provided (a gate valve through which a wafer is transferred into or from the transfer chamber 5 is omitted from this figure). The transfer chamber is also provided with an exhaust line 6

In some embodiments, the anisotropic etching, the deposition of films and surface treatments may be performed in the same reaction space, so that all the steps can continuously be conducted without exposing the substrate to air or other oxygen-containing atmosphere. In some embodiments, a remote plasma unit can be used for exciting a gas.

In some embodiments the substrate may be moveable relative to multiple reaction chamber such that some of the processing steps can be done in separate reaction chambers.

A skilled artisan will appreciate that the apparatus may include one or more controller(s) (not shown) programmed or otherwise configured to cause a reactor cleaning processes described elsewhere herein to be conducted. The controller(s) are communicated with the various power sources, heating systems, pumps, robotics, and gas flow controllers or valves of the reactor, as will be appreciated by the skilled artisan.

Referring to FIG. 2 in a second step 120 a first reactant may be provided to the surface. The first reactant may comprise an organosilicon compound e.g. tetraorganosilane. The organosilicon compound may have methyl end groups. The organosilicon compound may comprises tetramethylsilane which is less deposited on the side wall. The organosilicon compound may comprises a carbon terminated silicon precursor. The organosilicon compound may comprise nitrogen. The first organosilicon may be silanol, siloxane, or silane alkoxide. The first reactant may be a silazane for SiN deposition. The first reactant may be provided through the line 22, through the shower plate 4 into the reaction chamber 3 (see FIG. 1).

During step 120 in FIG. 2 a sputtering plasma may optionally be created to create sputtering in a top area of the surface whereby material from the top area may be relocated in the bottom of the gap. The sputtering plasma may comprise an oxygen, hydrogen, nitrogen, helium or argon plasma or any mixture thereof. The composition and quality of the deposited film can be controlled by the plasma condition e.g. SiO deposition may be controlled by using an oxygen plasma or SiN deposition may be controlled by using an nitrogen/hydrogen mixture.

To improve the sputtering effect the first reactant may have a large size and may be weakly chemisorbed. The sputtering plasma may be created by providing an oxygen, hydrogen, nitrogen, helium or argon plasma or any mixture thereof, for example through the line 21, through the shower plate 4 into the reaction chamber 3 of FIG. 1.

Excess reactant and byproduct may be removed after the first and second step 110, 120 to prevent reactions occurring elsewhere in the apparatus. The deposition method may be repeated multiple cycles to fill the gap from the bottom to the top such that the refilling material will not form a constriction near the top of the gap before the gap is completely filled.

It is to be understood that the configurations and/or approaches described herein are exemplary in nature, and that these specific embodiments or examples are not to be considered in a limiting sense, because numerous variations are possible. The specific routines or methods described herein may represent one or more of any number of processing strategies. Thus, the various acts illustrated may be performed in the sequence illustrated, in other sequences, or omitted in some cases.

The subject matter of the present invention includes all novel and nonobvious combinations and sub-combinations of the various processes, systems, and configurations, and other features, functions, acts, and/or properties disclosed herein, as well as any and all equivalents thereof. 

The invention claimed is:
 1. A method for filling one or more gaps created during manufacturing of a feature on a substrate by providing a deposition method comprising: in a cycle, providing an anisotropic plasma comprising a noble gas to bombard a bottom area of a surface of the one or more gaps with ions thereby creating adsorption sites comprising dangling bonds for a first reactant at the bottom area; in the cycle, after the step of providing an anisotropic plasma, introducing the first reactant to the substrate; and, in the cycle, allowing the first reactant to react with the created adsorption sites at the bottom area of the surface relative to side walls of the surface to deposit material on the bottom surface relative to the side walls, and repeating the cycle to fill the one or more gaps from the bottom area upwards, wherein during introducing the first reactant, a sputtering plasma is created by providing a sputtering gas to relocate material in a top area of the surface relative to the bottom area of the surface.
 2. The method of claim 1, wherein the method comprises removing excess reactant and byproduct from the reaction chamber after providing the anisotropic plasma and/or introducing the first reactant.
 3. The method according to claim 1, wherein the first reactant comprises a methyl end group.
 4. The method according to claim 1, wherein the noble gas plasma comprises a helium plasma.
 5. The method according to claim 1, wherein the noble gas plasma comprises an argon plasma.
 6. The method according to claim 1, wherein further comprising grounding a lower electrode.
 7. The method according to claim 1, wherein the sputtering plasma comprises a hydrogen plasma.
 8. The method according to claim 1, wherein the sputtering plasma comprises a nitrogen plasma.
 9. The method according to claim 1, wherein the sputtering plasma comprises an oxygen plasma.
 10. The method according to claim 1, wherein the sputtering plasma comprises an argon plasma.
 11. The method according to claim 1, wherein the first reactant comprises an organosilicon compound.
 12. The method according to claim 11, wherein the organosilicon compound comprises a tetraorganosilane.
 13. The method according to claim 11, wherein the organosilicon compound comprises methyl end groups.
 14. The method according to claim 11, wherein the organosilicon compound comprises tetramethylsilane.
 15. The method according to claim 11, wherein the organosilicon compound comprises a carbon terminated silicon precursor.
 16. The method according to claim 11, wherein the organosilicon compound comprises nitrogen.
 17. The method according to claim 11, wherein the first reactant comprises silanol.
 18. The method according to claim 11, wherein the first reactant comprises siloxane.
 19. The method according to claim 11, wherein the first reactant comprises a silane alkoxide.
 20. The method according to claim 1, wherein the first reactant comprises silazane.
 21. A semiconductor processing apparatus comprising: one or more reaction chambers for accommodating a substrate provided with one or more gaps created during manufacturing of a feature on the substrate; a plasma gas source comprising a noble gas for a plasma gas in gas communication via a plasma gas valve with one of the reaction chambers; a radio frequency power source constructed and arranged to create an anisotropic plasma of the plasma gas between two parallel plates in at least one of the one or more reaction chambers to bombard a bottom of a surface relative to side walls of the one or more gaps with ions thereby creating adsorption sites at the bottom; a first source for a first reactant in gas communication via a first valve with the at least one of the reaction chambers; and, a controller operably connected to the plasma and first gas valve, and the radio frequency power source and configured and programmed to control: a timing and an amount of the plasma gas, via the plasma gas valve, and the radio frequency source to use the plasma gas source and the radiofrequency power source to create an anisotropic plasma to bombard the bottom of the surface of the one or more gaps with ions thereby creating adsorption sites comprising dangling bonds for a first reactant at the bottom; and, after the step of the timing and an amount of the plasma gas, a timing and an amount of the first reactant to deposit the first reactant in the bottom of the surface of the one or more gaps to react with the created adsorption sites at the bottom of the surface relative to the side walls, wherein one of the two parallel plates is grounded. 